Fundamental study to grow single crystals with high performances operated up to high temperatures in donor-doped materials for energy harvesting

초록

An energy-harvesting material with high energy-conversion constant (d33 x g33) and Curie temperature (TC) is required to effectively harvest the mechanical energy which has not been recycled into electrical energy. Here, we present an eco-friendly single-crystals, the 3rd generation material, for energy harvesting with the excellent d33 x g33 of 118 10-12 m2N-1 (d33=1030 pCN-1) and high TC of 390 degrees C, prepared by simple heat-treatment. A donor (not an acceptor) has been doped to (K,Na)NbO3 (KNN)-based materials to obtain single-crystals through exceptionally abnormal grain growth (AGG). The severe AGG in a donor-doped KNN is explained by the donor effect to locally accelerate the volatilization of metals earlier. In particular, a donor-doped PbTiO3 (PT + Bi3+) material as well as a donor-doped KNN material allows for the synthesis of a single-crystal seed through the simple molten salt method. These findings advance understanding of sintering mechanisms in metal-volatile oxides and offer significant progress in energy-harvesting materials.

키워드