Electrical Resistivity of Natural Graphite-Fluorine Resin Composite for Bipolar Plates of Phosphoric Acid Fuel Cell(PAFC) Depending on Graphite Particle Size

초록

A composite material was prepared for the bipolar plates of phosphoric acid fuel cells(PAFC) by hot pressing a flake type natural graphite powder as a filler material and a fluorine resin as a binder. Average particle sizes of the powders were 610.3, 401.6, 99.5, and 37.7 mu m. The density of the composite increased from 2.25 to 2.72 g/cm(3) as the graphite size increased from 37.7 to 610.3 mu m. The anisotropy ratio of the composite increased from 1.8 to 490.9 as the graphite size increased. The flexural strength of the composite decreased from 15.60 to 8.94MPa as the graphite size increased. The porosity and the resistivity of the composite showed the same tendencies, and decreased as the graphite size increased. The lowest resistivity and porosity of the composite were 1.99 x 10(-3) Omega cm and 2.02 %, respectively, when the graphite size was 401.6 mu m. The flexural strength of the composite was 10.3MPa when the graphite size was 401.6 mu m. The lowest resistance to electron mobility was well correlated with the composite with lowest porosity. It was possible the flaky large graphite particles survive after the hot pressing process.

키워드